Energetics

8.3 ENTHALPY OF REACTION

The amount of heat or thermal energy evolved or absorbed in a chemical reaction is called enthalpy of reaction. Its sign is negative for exothermic and positive for endothermic reactions. Enthalpy of reaction measured at 25°C (or 298K) and one atmospheric pressure is known as standard enthalpy change. It is denoted by ΔH°.

Examples:

  • C(s) + O2(g) → CO2(g) ΔH° = -393.5 kJ
  • H2(g) + 1/2 O2(g) → 2HI(g) ΔH° = +53.8 kJ

Which of the above reactions is endothermic?